There are two parts to backing up your WordPress site: Database and Files.
This page talks about Files only; if you need to back up your WordPress database, see the Backing Up Your Database.
Your WordPress site consists of the following files:
Everything that has anything to do with the look and feel of your site is in a file somewhere and needs to be backed up. Additionally, you must back up all of your files in your WordPress directory (including subdirectories) and your .htaccess file.
While most hosts back up the entire server, including your site, it is better that you back up your own files. The easiest method is to use an FTP program to download all of your WordPress files from your host to your local computer.
By default, the files in the directory called wp-content are your own user-generated content, such as edited themes, new plugins, and uploaded files. Pay particular attention to backing up this area, along with your wp-config.php, which contains your connection details. The remaining files are mostly the core files, which are supplied by the WordPress download zip file.
Please read Backing Up Your WordPress Site for further information.
Other ways to backup your files include:
To synchronize your files in WinScp -
Normally, there would be no need to copy the WordPress core files, as you can replace them from a fresh download of the WordPress zip file. The important files to back up would be your wp-config.php file, which contains your settings and your wp-content directory (plus its contents) which contains all your theme and plugin files